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Contemporary Materials 2016 - Савремени Материјали - confOrganiser.com

Contemporary Materials 2016 - Савремени Материјали

4 - 5.9.2016.

ANALYSIS OF ZSM-5 CATALYST MICROPOROUS STRUCTURE BY NITROGEN ADSORPTION AT 77 K

Аутори:
1. Rada Petrovic, Faculty of Technology Banja Luka, Republic of Srpska, Bosnia and Herzegovina
2. Jelena Penavin-Škundrić, Природно-математички факултет Бања Лука, Republic of Srpska, Bosnia and Herzegovina
3. Бранко Шкундрић, Академија наука и умјетности Републике Српске, Republic of Srpska, Bosnia and Herzegovina
4. Зорица Леви, Faculty of Technology Banja Luka, Republic of Srpska, Bosnia and Herzegovina
5. Dragica Lazić, Republic of Srpska, Bosnia and Herzegovina
6. Дарко Бодрожа, Republic of Srpska, Bosnia and Herzegovina
7. Gordana Ostojic, Republic of Srpska, Bosnia and Herzegovina


Апстракт:
Abstract: The paper examined microporous structure of ZSM-5 zeoliteand its cation modified forms: Fe-ZSM-5, Cu-ZSM-5, Co-ZSM-5, Mn-ZSM-5 and Ni-ZSM-5 zeoliteby the adsorption of nitrogen at 77 K. Specific surface (SP) of the mentioned ZSM-5 zeolites was determined by the use of BET-equation (SPBET) and Langmuir equation (SPLANG), while „t-method“ was used for determining the outer specific surface (SPext) and for estimating the volume of micropores (Vμpt). Dubinin Radushkevich equation (VμpDR) was also used for estimating the volume of micropores. It was established that the presence of: Fe2+, Cu2+, Co2+, Mn2+and Ni2+ ions in the structure of ZSM-5 zeolite results in a minor increase of the specific surface (SPBET) and a minor decrease of the outer specific surface (SPext).

Кључне речи:
ZSM-5 zeolite, adsorption of nitrogen, specific surface, porosity

Тематска област:
СИМПОЗИЈУМ А - Наука материје, кондензоване материје и физикa чврстог стања

Датум пријаве сажетка:
30.06.2016.

Конференцијa:
Contemporary Materials 2016 - Савремени Материјали

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